Background Information: Phenolphthalein (phen) is an
indicator that is colorless in an
acid and bright pink in a base.
Purpose: To determine the molarity of three acids – citric acid, vinegar, and soda.
Hypothesis: Before you begin the experiment, hypothesize. Predict which substance will have the highest molarity? The lowest?
Procedure:
- Add 10 drops of acid to a clean, rinsed cup. Add 1 drop of phen, the indicator.
- Add 0.1 M NaOH, drop by drop to the acid until the color turns pink.
- Record the number of drops of NaOH needed to reach neutralization.
- Rinse and dry the cup before going onto the next trial.
If time allows, repeat each experiment twice.
Data:
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Number of drops of 0.10 M NaOH
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Trial #1
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Trial #2
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10 drops of vinegar
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10 drops of soda
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The balanced equations for the reactions:
Citric acid: H
3C
6H
5O
7 + 3 NaOH
3 H
2O + Na(C
6H
5O
7)
3
Vinegar: HC
2H
3O
2 + 1 NaOH

H
2O + NaC
2H
3O
2
Soda: H
2CO
3 + 2 NaOH

H
2O + Na
2CO
3
Find the molarity of each acid.
Conclusion: All three of these acids are weak, but obviously, they vary in strength. Rank them from least to most acidic.